A water-based battery design aims at safety and longevity
Researchers in China have reported an aqueous battery chemistry that they say could dramatically extend the working life of grid-scale energy storage while avoiding some of the disposal and safety problems tied to conventional lithium-ion systems. The work, published Feb. 18 in Nature Communications, centers on a class of synthesized covalent organic polymers used as the anode in a battery that carries magnesium and calcium ions through a neutral water-based electrolyte.
The headline claim is striking: the team says the battery can last for roughly 120,000 charge cycles, or more than 10 times the life of a typical lithium-ion battery used for grid storage. Just as notable, the researchers argue that the chemistry avoids toxic elements and can be disposed of safely in the environment, making it an unusually clean candidate for large stationary storage systems.
Why aqueous batteries matter
Aqueous batteries have long attracted attention because water-based electrolytes are nonflammable and can be cheaper than the materials used in many mainstream battery designs. That makes them an appealing option for applications such as renewable energy buffering, where low fire risk and long operating life can matter as much as energy density.
But the format has a stubborn weakness. Organic polymers, which can be useful in these batteries, often break down quickly in the acidic or alkaline electrolytes commonly used in aqueous systems. That degradation undercuts the very advantage that utilities and grid operators care about most: dependable performance over many years of cycling.
The new study tries to solve that problem by changing both the battery’s structural chemistry and the operating environment inside the cell. Instead of relying on harsh electrolytes, the researchers used a neutral electrolyte with a pH of 7.0. They paired that with a specific compound described as hexaketone-tetraaminodibenzo-p-dioxin, which combines carbonyl-rich regions that attract positive ions with a rigid molecular scaffold that helps the material retain a flat, honeycomb-like structure.







